Okay here is step 1:
1. select two or three photos
a. Look at your photos... select ONE color to highlight (perhaps the most vibrant, or the color of the most 'important' item in the photo). If you can, get the hexadecimal color code I'll refer to this as the 'primary' color.
PSE tip: to get the hexadecimal color code, use the eyedropper tool. See help here: http://help.adobe.com/en_US/Photosho...23F39_WIN.html
b. Go to http://www.colorschemedesigner.com/ and select the "complementary" color palette (click on the "complement" link on the upper left)
To enter your hex code on colorschemedesigner, look for the "RGB" at the lower right of the wheel